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Unlocking fuel cell conductivity (Vol. 44 No. 3)

Temperature dependence of conductivity data of bulk YSZ

Yttria stabilized zirconia, also known as YSZ, is a material of great interest because of its relatively high oxygen-ion based conductivity. In particular, it finds applications in electrochemical devices, such as solid oxide fuel cells and oxygen sensors. The present work developes a model of the oxygen-ion dynamics contributing to the conductivity of YSZ. The problem is that fuel cells currently operate above 700 ºC, which strongly limits their use. Understanding oxygen-ion diffusion is key in helping lower operating temperature towards ambient. Previous attempts to do so were done with the so-called coupling model (CM), describing simple physical concepts related to ion-ion interaction. This helped uncover the importance of ion-ion correlation in limiting long-range ion mobility, and thus conductivity.

The trouble is that experiments show that ionic conductivity in YSZ requires an activation energy that is much higher than that supplied by computer simulations describing independent ion hopping. Relying on the CM model, the authors first established a quantitative description of the ion dynamics in YSZ. Then they compared the predictions of the CM with experimental results and with simulations, particularly those of nanometric-scale thin films, published in the last ten years.

Thus, the present model establishes the connection between the level of the energy barrier for independent ion-hopping simulations and the level of activation energy of long-range oxygen ions measured experimentally. This model could also be used to study the conductivity relaxation of so-called molten, glassy and crystalline ionic conductors and ambient temperature ionic liquids.

K. L. Ngai, J. Santamaria and C. Leon, ‘Dynamics of interacting oxygen ions in yttria stabilized zirconia: bulk material and nanometer thin films’, Eur. Phys. J. B, 86, 7 (2013)
[Abstract]

A customized THz quantum-cascade laser (Vol. 44 No. 3)

Frequency tuning using the applied current and beam profile of the local oscillator. The gray horizontal solid line indicates the frequency of the oxygen line.

Quantum-cascade lasers for the terahertz spectral region are promising light sources for several spectroscopic applications, despite currently only operating at cryogenic temperatures. The authors developed a local oscillator to be used in an airborne heterodyne receiver for the investigation of interstellar atomic oxygen. The challenge for the design consists in the simultaneous fulfilment of demanding specifications for a set of operating parameters.

The developed laser emits a single mode with an optical power of about 0.5 mW and an almost Gaussian beam shape. The laser mode can be tuned using the applied current to cover about 5 GHz in the vicinity of 4.745 THz. The local oscillator, which is based on a distributed-feedback laser combining a quantum-cascade laser with a single-plasmon waveguide and a lateral first-order grating, can be operated in a cryogen-free cooler in continuous-wave mode. The developed quantum-cascade laser exhibits large wall-plug efficiency over a wide range of current densities with a negligible spectral shift of the gain maximum in order to achieve the required tuning range.

L. Schrottke, M. Wienold, R. Sharma, X. Lü, K. Biermann, R. Hey, A. Tahraoui, H. Richter, H.-W. Hübers, and H. T. Grahn, ‘Quantum-cascade lasers as local oscillators for heterodyne spectrometers in the spectral range around 4.745 THz’, Semicond. Sci. Technol. 28, 035011 (2013).
[Abstract]

Gauge theory of topological phases of matter (Vol. 44 No. 3)

Topologically protected states of matter are the focus of recent intensive research efforts. Such states may play an important role in future concrete implementations of devices for topological quantum computing. Prominent examples are incompressible 2D electron gases exhibiting the Quantum Hall effect or the spin Hall effect, 3D topological insulators and superconductors, etc. From a conceptual point of view it is important to note that the low-energy effective theories describing all these states can be derived, using only very general principles, from a unified theoretical framework which we have called “gauge theory of states of matter”.

A key idea underlying our framework is to promote fundamental or emergent global symmetries of idealized systems to local gauge symmetries of realistic systems, and to then study the response of such systems under variations of the corresponding gauge fields. For systems with a bulk energy gap, our theory predicts the general form of the response laws, transport equations, and the structure of gapless surface modes. It also elucidates how the structure of the ionic background, electromagnetic fields, velocity fields and curvature influence the properties of such systems.

J. Fröhlich and P. Werner, ‘Gauge theory of topological phases of matter’, EPL, 101, 47007 (2013)
[Abstract]

Measuring Higgs couplings at a linear collider (Vol. 44 No. 3)

Expected precision for Higgs coupling measurements for the HL-LHC, ILC and the combination of the HL-LHC and the ILC.

In 2012 the experiments ATLAS and CMS discovered a new particle in proton-proton collisions at CERN's Large Hadron Collider (LHC). The measurements show that the properties of the particle are compatible with those predicted for the Higgs boson of the Standard Model. In the article we estimate the precision with which some of the fundamental properties of the particle, its couplings to other particles, can be measured including theoretical errors, at a high-luminosity LHC (HL-LHC), a linear electron-positron collider and the combination of the two. The uncertainties are expected to be better than 1% for a single parameter modifying all Higgs couplings simultaneously, and at the percent level if all relevant couplings are left free and independent of each other. The combination of the measurements at the two machines improves on the uncertainty of each one of these. Thus a HL-LHC and a linear collider form a dream team to study the properties of the Higgs boson with high precision.

M. Klute, R. Lafaye, T. Plehn, M. Rauch and D. Zerwas, ‘Measuring Higgs couplings at a linear collider’, EPL, 101, 51001 (2013)
[Abstract]